Linked Life Data

16365649

Source:http://linkedlifedata.com/resource/pubmed/id/16365649

Statements in which the resource exists.
SubjectPredicateObjectContext
pubmed-article:16365649rdf:typepubmed:Citationlld:pubmed
pubmed-article:16365649lifeskim:mentionsumls-concept:C0024706lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0220781lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C1704332lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0007996lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0444669lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C1883254lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0024488lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0563532lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0678594lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0679622lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0205314lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0871161lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0178528lld:lifeskim
pubmed-article:16365649lifeskim:mentionsumls-concept:C0077190lld:lifeskim
pubmed-article:16365649pubmed:issue2lld:pubmed
pubmed-article:16365649pubmed:dateCreated2005-12-20lld:pubmed
pubmed-article:16365649pubmed:abstractTextThe reaction between MnBr(2).4H(2)O with H(3)tmp (1,1,1-tris(hydroxymethyl)propane) in MeCN in the presence of Na(O(2)CCMe(3)) and NBu(4)Br produces the complex [Mn(8)(O(2)CCMe(3))(2)(tmp)(2)(Htmp)(4)Br(4)(H(2)O)(2)].2MeCN (1.2MeCN) in good yield. The centrosymmetric octanuclear molecule consists of four Mn(III) and four Mn(II) ions assembled together by fourteen alkoxo bridges to give a [Mn(III)(4)Mn(II)(4)(mu(3)-OR)(6)(mu(2)-OR)(8)](6+) rod-like core in which the metal centres are arranged in a planar zigzag fashion. Peripheral ligation is provided by a combination of bridging pivalate ions, terminal bromides and water molecules. Dc magnetic susceptibility measurements reveal the presence of dominant antiferromagnetic interactions leading to a spin ground state of S = 0. A rationalization of this result is attempted by structural comparison with previously reported tetranuclear manganese complexes containing the [Mn(III)(2)Mn(II)(2)(mu(3)-OR)(2)(mu(2)-OR)(4)] core in which the magnetic interactions are ferromagnetic.lld:pubmed
pubmed-article:16365649pubmed:languageenglld:pubmed
pubmed-article:16365649pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:citationSubsetIMlld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:chemicalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:16365649pubmed:statusMEDLINElld:pubmed
pubmed-article:16365649pubmed:monthJanlld:pubmed
pubmed-article:16365649pubmed:issn1477-9226lld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:ChristouGeorg...lld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:ParsonsSimonSlld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:BrechinEuan...lld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:MurugesuMural...lld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:MiliosConstan...lld:pubmed
pubmed-article:16365649pubmed:authorpubmed-author:FabbianiFranc...lld:pubmed
pubmed-article:16365649pubmed:issnTypePrintlld:pubmed
pubmed-article:16365649pubmed:day14lld:pubmed
pubmed-article:16365649pubmed:ownerNLMlld:pubmed
pubmed-article:16365649pubmed:authorsCompleteYlld:pubmed
pubmed-article:16365649pubmed:pagination351-6lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:meshHeadingpubmed-meshheading:16365649...lld:pubmed
pubmed-article:16365649pubmed:year2006lld:pubmed
pubmed-article:16365649pubmed:articleTitle1,1,1-Tris(hydroxymethyl)propane in manganese carboxylate chemistry: synthesis, structure and magnetic properties of a mixed-valence [MnIII4MnII4] cluster featuring the novel [MnIII4MnII4(mu3-OR)6(mu2-OR)8]6+ core.lld:pubmed
pubmed-article:16365649pubmed:affiliationSchool of Chemistry, The University of Edinburgh, UK.lld:pubmed
pubmed-article:16365649pubmed:publicationTypeJournal Articlelld:pubmed