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pubmed-article:16302764pubmed:abstractTextTwo major anthocyanins were isolated from the acidified methanolic extract of eggplant (Solanum melongena L.) by column chromatography and preparative high-performance liquid chromatography. These anthocyanins were interconvertible under room light illumination condition. By means of tandem time-of-flight mass spectrometry and nuclear magnetic resonance spectroscopy, their structures were identified and elucidated as delphinidin 3-[4-(cis-p-coumaroyl)-l-rhamnosyl(1-->6)glucopyranoside]-5-glucopyranoside (compound 1) and delphinidin 3-[4-(trans-p-coumaroyl)-l-rhamnosyl-(1-->6)glucopyranoside]-5-glucopyranoside (compound 2), respectively. The results indicated that nasunin comprised cis and trans isomers of the p-coumaric acid moiety in its structure.lld:pubmed
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pubmed-article:16302764pubmed:authorpubmed-author:ShidaYasuoYlld:pubmed
pubmed-article:16302764pubmed:authorpubmed-author:KaneyukiTakao...lld:pubmed
pubmed-article:16302764pubmed:authorpubmed-author:KashiwadaYosh...lld:pubmed
pubmed-article:16302764pubmed:authorpubmed-author:IchiyanagiTak...lld:pubmed
pubmed-article:16302764pubmed:authorpubmed-author:IkeshiroYasum...lld:pubmed
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pubmed-article:16302764pubmed:pagination9472-7lld:pubmed
pubmed-article:16302764pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:16302764pubmed:articleTitleNasunin from eggplant consists of cis-trans isomers of delphinidin 3-[4-(p-coumaroyl)-L-rhamnosyl (1-->6)glucopyranoside]-5-glucopyranoside.lld:pubmed
pubmed-article:16302764pubmed:affiliationFaculty of Applied Life Sciences, Niigata University of Pharmacy and Applied Life Sciences, 265-1 Higashijima, Niigata 956-8603, Japan. kouji@niigata-pharm.ac.jplld:pubmed
pubmed-article:16302764pubmed:publicationTypeJournal Articlelld:pubmed