Source:http://linkedlifedata.com/resource/pubmed/id/16224762
| Subject | Predicate | Object | Context |
|---|---|---|---|
| pubmed-article:16224762 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0302934 | lld:lifeskim |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0237753 | lld:lifeskim |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0205360 | lld:lifeskim |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0678594 | lld:lifeskim |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0337189 | lld:lifeskim |
| pubmed-article:16224762 | lifeskim:mentions | umls-concept:C0441239 | lld:lifeskim |
| pubmed-article:16224762 | pubmed:issue | 2 | lld:pubmed |
| pubmed-article:16224762 | pubmed:dateCreated | 2005-12-26 | lld:pubmed |
| pubmed-article:16224762 | pubmed:abstractText | The production, isolation, and spectroscopic characterization of a new Dy3N@C80 cluster fullerene that exhibits three isomers (1-3) is reported for the first time. In addition, the third isomer (3) forms a completely new C80 cage structure that has not been reported in any endohedral fullerenes so far. The isomeric structures of the Dy3N@C80 cluster fullerene were analyzed by studying HPLC retention behavior, laser desorption time-of-flight (LD-TOF) mass spectrometry, and UV-Vis-NIR and FTIR spectroscopy. The three isomers of Dy3N@C80 were all large band-gap (1.51, 1.33, and 1.31 eV for 1-3, respectively) materials, and could be classified as very stable fullerenes. According to results of FTIR spectroscopy, the Dy3N@C80 (I) (1) was assigned to the fullerene cage C80:7 (I(h)), whereas Dy3N@C80 (II) (2) had the cage structure of C80:6 (D(5h)). The most probable cage structure of Dy3N@C80 (III) (3) was proposed to be C80:1 (D(5d)). The significant differences between Dy3N@C80 and other reported M3N@C80 (M = Sc, Y, Gd, Tb, Ho, Er, Tm) cluster fullerenes are discussed in detail, and the strong influence of the metal on the nitride cluster fullerene formation is concluded. | lld:pubmed |
| pubmed-article:16224762 | pubmed:language | eng | lld:pubmed |
| pubmed-article:16224762 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16224762 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:16224762 | pubmed:month | Dec | lld:pubmed |
| pubmed-article:16224762 | pubmed:issn | 0947-6539 | lld:pubmed |
| pubmed-article:16224762 | pubmed:author | pubmed-author:DunschLotharL | lld:pubmed |
| pubmed-article:16224762 | pubmed:author | pubmed-author:YangShangfeng... | lld:pubmed |
| pubmed-article:16224762 | pubmed:issnType | lld:pubmed | |
| pubmed-article:16224762 | pubmed:day | 23 | lld:pubmed |
| pubmed-article:16224762 | pubmed:volume | 12 | lld:pubmed |
| pubmed-article:16224762 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:16224762 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:16224762 | pubmed:pagination | 413-9 | lld:pubmed |
| pubmed-article:16224762 | pubmed:dateRevised | 2009-8-4 | lld:pubmed |
| pubmed-article:16224762 | pubmed:year | 2005 | lld:pubmed |
| pubmed-article:16224762 | pubmed:articleTitle | Expanding the number of stable isomeric structures of the C80 cage: a new fullerene Dy3N@C80. | lld:pubmed |
| pubmed-article:16224762 | pubmed:affiliation | Group of Electrochemistry and Conducting Polymers, Leibniz-Institute for Solid State and Materials Research Dresden, 01171 Dresden, Germany. s.yang@ifw-dresden.de | lld:pubmed |
| pubmed-article:16224762 | pubmed:publicationType | Journal Article | lld:pubmed |