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pubmed-article:15949749rdf:typepubmed:Citationlld:pubmed
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pubmed-article:15949749pubmed:dateCreated2005-6-13lld:pubmed
pubmed-article:15949749pubmed:abstractTextMetal ion complexes provide flexible paramagnetic centers that may be used to define intermolecular contacts in a variety of solution phase environments because both the charge and electronic relaxation properties of the complex may be varied. For most complex ions, there are several proton equilibria that may change the effective charge on the complex as a function of pH which in turn affects the efficacy of application for defining the electrostatic surfaces of co-solute molecules. We report here spectrophotometric and nuclear spin relaxation studies on aqueous solutions of chromium(III) complexes of EDTA, DTPA, and bis-amides of both. The effective charges available from these paramagnetic centers range from -3 to +1 and we report the pH ranges over which the effective charge is defined with confidence for application in magnetic relaxation experiments.lld:pubmed
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pubmed-article:15949749pubmed:statusMEDLINElld:pubmed
pubmed-article:15949749pubmed:monthJullld:pubmed
pubmed-article:15949749pubmed:issn1090-7807lld:pubmed
pubmed-article:15949749pubmed:authorpubmed-author:BryantR GRGlld:pubmed
pubmed-article:15949749pubmed:authorpubmed-author:VictorKenKlld:pubmed
pubmed-article:15949749pubmed:authorpubmed-author:DiakovaGalina...lld:pubmed
pubmed-article:15949749pubmed:authorpubmed-author:FullerZachary...lld:pubmed
pubmed-article:15949749pubmed:authorpubmed-author:FuminoKoichiKlld:pubmed
pubmed-article:15949749pubmed:issnTypePrintlld:pubmed
pubmed-article:15949749pubmed:volume175lld:pubmed
pubmed-article:15949749pubmed:ownerNLMlld:pubmed
pubmed-article:15949749pubmed:authorsCompleteYlld:pubmed
pubmed-article:15949749pubmed:pagination65-72lld:pubmed
pubmed-article:15949749pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:15949749pubmed:year2005lld:pubmed
pubmed-article:15949749pubmed:articleTitleChromium(III) complexes as intermolecular probes.lld:pubmed
pubmed-article:15949749pubmed:affiliationChemistry Department, University of Virginia, Charlottesville, VA 22904-4319, USA.lld:pubmed
pubmed-article:15949749pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:15949749pubmed:publicationTypeComparative Studylld:pubmed
pubmed-article:15949749pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed
pubmed-article:15949749pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
pubmed-article:15949749pubmed:publicationTypeEvaluation Studieslld:pubmed
pubmed-article:15949749pubmed:publicationTypeResearch Support, N.I.H., Extramurallld:pubmed