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pubmed-article:15924315pubmed:issue3lld:pubmed
pubmed-article:15924315pubmed:dateCreated2005-6-2lld:pubmed
pubmed-article:15924315pubmed:abstractTextA flow-injection chemiluminescent method for the determination of oxytetracycline was developed. The method is based on an enhancement by oxytetracycline of the chemiluminescence light emission of tris(2,2'-bipyridine) ruthenium (II), generated by the continuous oxidation of tris(2,2'-bipyridine) ruthenium (II) by cerium (IV) sulphate in sulphuric acid. Under the optimum conditions, the calibration curve was linear over the range 1.0 x 10(-7)-1.0 x 10(-5) g/mL for oxytetracycline with the linear equation: DeltaINT = 148.77 x C + 0.6637 (R2 = 0.9994). The detection limit was 4.52 x 10(-8) g/mL. The proposed method was also successfully used to determine oxytetracycline in pharmaceutical formulations. The mean recovery of determination of oxytetracycline was 92.73%. A mechanism for the chemiluminescence enhancement by oxytetracycline of tris(2,2'-bipyridine)-ruthenium (II) and cerium (IV) sulphate system is also proposed.lld:pubmed
pubmed-article:15924315pubmed:languageenglld:pubmed
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pubmed-article:15924315pubmed:statusMEDLINElld:pubmed
pubmed-article:15924315pubmed:issn1522-7235lld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:ChenGuonanGlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:ZhangWeilinWlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:LiuXiaohuaXlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:GuoLiangqiaLlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:XieZenghongZlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:LinXucongXlld:pubmed
pubmed-article:15924315pubmed:authorpubmed-author:BianXintongXlld:pubmed
pubmed-article:15924315pubmed:copyrightInfoCopyright 2005 John Wiley & Sons, Ltd.lld:pubmed
pubmed-article:15924315pubmed:issnTypePrintlld:pubmed
pubmed-article:15924315pubmed:volume20lld:pubmed
pubmed-article:15924315pubmed:ownerNLMlld:pubmed
pubmed-article:15924315pubmed:authorsCompleteYlld:pubmed
pubmed-article:15924315pubmed:pagination129-34lld:pubmed
pubmed-article:15924315pubmed:dateRevised2011-11-17lld:pubmed
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pubmed-article:15924315pubmed:articleTitleDetermination of oxytetracycline by flow injection with chemiluminescence detection.lld:pubmed
pubmed-article:15924315pubmed:affiliationDepartment of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, People's Republic of China.lld:pubmed
pubmed-article:15924315pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:15924315pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed