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pubmed-article:15847509pubmed:abstractTextSwitching of molecular chirality under photo-irradiation was studied in a cobaloxime complex crystal. Excitation of the d-d transition of the Co(III) ion appeared to be much more effective in inducing the chirality change than excitation of the ligand-metal charge transfer band although the latter is more effective in breaking the Co-C bond that initiates the chirality switching. The chirality change versus irradiation time showed a steplike behavior suggesting that chirality switching of molecules occurred in correlation with their nearest neighbors.lld:pubmed
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pubmed-article:15847509pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:15847509pubmed:articleTitlePhoto-induced chirality switching in a cobaloxime complex crystal.lld:pubmed
pubmed-article:15847509pubmed:affiliationDepartment of Materials Science, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8551, Japan. kikeda@chem.titech.ac.jplld:pubmed
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