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pubmed-article:15783190rdf:typepubmed:Citationlld:pubmed
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pubmed-article:15783190pubmed:dateCreated2005-3-23lld:pubmed
pubmed-article:15783190pubmed:abstractTextThe preparation and circular dichroic (CD) studies of self-complimentary 8-mer DNA sequences with a porphyrin at the 3' end are presented. Electronic interaction between the two porphyrins (the interchromophoric distance is in the range of 28-40 A), attached to both ends of the double-stranded helix, gives rise to a long-range exciton-coupled CD in the visible region (400-450 nm). The porphyrin chromophores act as sensitive probes of geometrical changes in the DNA backbone and sensitively reflect the double-strand to single-strand transition. This study demonstrates the possibility of using exciton-coupled porphyrin CDs for conformational studies of DNA.lld:pubmed
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pubmed-article:15783190pubmed:authorpubmed-author:NakanishiKoji...lld:pubmed
pubmed-article:15783190pubmed:authorpubmed-author:BerovaNinaNlld:pubmed
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pubmed-article:15783190pubmed:authorpubmed-author:BalazMilanMlld:pubmed
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pubmed-article:15783190pubmed:day30lld:pubmed
pubmed-article:15783190pubmed:volume127lld:pubmed
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pubmed-article:15783190pubmed:pagination4172-3lld:pubmed
pubmed-article:15783190pubmed:dateRevised2007-11-14lld:pubmed
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pubmed-article:15783190pubmed:year2005lld:pubmed
pubmed-article:15783190pubmed:articleTitleSynthesis and circular dichroism of tetraarylporphyrin-oligonucleotide conjugates.lld:pubmed
pubmed-article:15783190pubmed:affiliationDepartment of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA.lld:pubmed
pubmed-article:15783190pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:15783190pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed