| pubmed-article:15624179 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:15624179 | lifeskim:mentions | umls-concept:C0036581 | lld:lifeskim |
| pubmed-article:15624179 | lifeskim:mentions | umls-concept:C1948027 | lld:lifeskim |
| pubmed-article:15624179 | lifeskim:mentions | umls-concept:C0201699 | lld:lifeskim |
| pubmed-article:15624179 | lifeskim:mentions | umls-concept:C0037802 | lld:lifeskim |
| pubmed-article:15624179 | lifeskim:mentions | umls-concept:C0936012 | lld:lifeskim |
| pubmed-article:15624179 | pubmed:issue | 1 | lld:pubmed |
| pubmed-article:15624179 | pubmed:dateCreated | 2005-1-10 | lld:pubmed |
| pubmed-article:15624179 | pubmed:abstractText | A new method for speciation analysis of two inorganic selenium species was developed by on-line coupling of capillary electrophoresis (CE) with hydride generation-atomic fluorescence spectrometry (HG-AFS) and on-line conversion of Se(VI) to Se(IV). Baseline separation of Se(VI) and Se(IV) was achieved by CE in a 50 cm x 75 microm inside diameter (ID) fused-silica capillary at -20 kV using a mixture of 15 mmol.L(-1) NaH2PO4 and 0.5 mmol.L(-1) cetyltrimethylammonium bromide (pH 7.5) as electrolyte buffer. Se(VI) was on-line reduced to Se(IV) by mixing the CE effluent with concentrated HCl. The precision (relative standard deviation, RSD, n=7) ranged from 0.7 to 1.3% for migration time, 6.4 to 3.7% for peak height response, and 5.9 to 6.1% for peak area for the two selenium species at the 500 microg.L(-1) (as Se) level. The detection limits were 33 and 25 microg.L(-1) (as Se) for Se(VI) and Se(IV), respectively. The recoveries of the two selenium species in five locally collected water samples ranged from 88 to 114%. The developed method was applied to speciation analysis of inorganic selenium species in spiked natural water samples. | lld:pubmed |
| pubmed-article:15624179 | pubmed:language | eng | lld:pubmed |
| pubmed-article:15624179 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15624179 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:15624179 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15624179 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15624179 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:15624179 | pubmed:month | Jan | lld:pubmed |
| pubmed-article:15624179 | pubmed:issn | 0173-0835 | lld:pubmed |
| pubmed-article:15624179 | pubmed:author | pubmed-author:YanXiu-PingXP | lld:pubmed |
| pubmed-article:15624179 | pubmed:author | pubmed-author:LuCai-YanCY | lld:pubmed |
| pubmed-article:15624179 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:15624179 | pubmed:volume | 26 | lld:pubmed |
| pubmed-article:15624179 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:15624179 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:15624179 | pubmed:pagination | 155-60 | lld:pubmed |
| pubmed-article:15624179 | pubmed:dateRevised | 2006-11-15 | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:meshHeading | pubmed-meshheading:15624179... | lld:pubmed |
| pubmed-article:15624179 | pubmed:year | 2005 | lld:pubmed |
| pubmed-article:15624179 | pubmed:articleTitle | Capillary electrophoresis on-line coupled with hydride generation-atomic fluorescence spectrometry for speciation analysis of selenium. | lld:pubmed |
| pubmed-article:15624179 | pubmed:affiliation | State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Research Center for Analytical Sciences, Department of Chemistry, Nankai University, Tianjin, China. | lld:pubmed |
| pubmed-article:15624179 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:15624179 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
| pubmed-article:15624179 | pubmed:publicationType | Evaluation Studies | lld:pubmed |
