| pubmed-article:15057554 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C0596901 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1364081 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1706554 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1707455 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1158204 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1709845 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C1280519 | lld:lifeskim |
| pubmed-article:15057554 | lifeskim:mentions | umls-concept:C0065973 | lld:lifeskim |
| pubmed-article:15057554 | pubmed:issue | 4 | lld:pubmed |
| pubmed-article:15057554 | pubmed:dateCreated | 2004-7-2 | lld:pubmed |
| pubmed-article:15057554 | pubmed:abstractText | Two membrane electrochemical reactors (MER) were designed and applied to HLADH-catalysed reduction of cyclohexanone to cyclohexanol. The regeneration of the cofactor NADH was ensured electrochemically, using either methyl viologen or a rhodium complex as electrochemical mediator. A semi-permeable membrane (dialysis or ultra-filtration) was integrated in the filter-press electrochemical reactor to confine the enzyme(s) as close as possible to the electrode surface. When methyl viologen was used, the transformation ratio of cyclohexanone varied from 0 to 65% depending on the internal arrangement of the reactor. Matching the reactor configuration to the reaction system was essential in this case. With the rhodium complex, the ultra-filtration MER was tested in continuous and recycling configurations. The best conditions led to 100% transformation of 0.1 L volume of 0.1 M cyclohexanone after 70 h with the recycling mode. Finally, the performances of the reactors are discussed with respect to different evaluations of the production yields. | lld:pubmed |
| pubmed-article:15057554 | pubmed:language | eng | lld:pubmed |
| pubmed-article:15057554 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:15057554 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:15057554 | pubmed:month | Jul | lld:pubmed |
| pubmed-article:15057554 | pubmed:issn | 1615-7591 | lld:pubmed |
| pubmed-article:15057554 | pubmed:author | pubmed-author:BergelAA | lld:pubmed |
| pubmed-article:15057554 | pubmed:author | pubmed-author:Délécouls-Ser... | lld:pubmed |
| pubmed-article:15057554 | pubmed:author | pubmed-author:BasséguyRR | lld:pubmed |
| pubmed-article:15057554 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:15057554 | pubmed:volume | 26 | lld:pubmed |
| pubmed-article:15057554 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:15057554 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:15057554 | pubmed:pagination | 205-15 | lld:pubmed |
| pubmed-article:15057554 | pubmed:dateRevised | 2006-11-15 | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
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| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:meshHeading | pubmed-meshheading:15057554... | lld:pubmed |
| pubmed-article:15057554 | pubmed:year | 2004 | lld:pubmed |
| pubmed-article:15057554 | pubmed:articleTitle | Membrane electrochemical reactors (MER) for NADH regeneration in HLADH-catalysed synthesis: comparison of effectiveness. | lld:pubmed |
| pubmed-article:15057554 | pubmed:affiliation | Laboratoire de Génie Chimique-CNRS UMR 5503, Basso Cambo, 5 rue Paulin Talabot, BP1301, 31106 Toulouse, France. | lld:pubmed |
| pubmed-article:15057554 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:15057554 | pubmed:publicationType | Comparative Study | lld:pubmed |
| pubmed-article:15057554 | pubmed:publicationType | Evaluation Studies | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:15057554 | lld:pubmed |
