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pubmed-article:14720541pubmed:abstractTextThe catalytic incineration of toluene over gamma-Al2O3-supported transition-metal oxide catalysts in the temperature range of 200-380 degrees C was investigated employing a fixed bed flow reactor. CuO/gamma-Al2O3 was found to be the most active of seven catalysts tested. Using this catalyst with different wt% Cu in the incineration of toluene, we found that the optimal Cu content was 5 wt%. X-ray diffraction, BET surface area and hydrogen-temperature-programmed reduction showed that it was mainly the formation of large CuO crystals that caused declines in catalyst activity at Cu content above 5 wt%. Addition of water vapor or CO2 inhibited catalyst activity, but this effect was reversible. Although coexistence of toluene and n-hexane resulted in a reduction in n-hexane conversion, the impact on toluene oxidation was only negligible. Temperature-programmed desorption revealed that this differential effect was due to more competitive adsorption of toluene onto active sites of the catalyst.lld:pubmed
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pubmed-article:14720541pubmed:authorpubmed-author:WangChing-Hue...lld:pubmed
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pubmed-article:14720541pubmed:year2004lld:pubmed
pubmed-article:14720541pubmed:articleTitleAl2O3-supported transition-metal oxide catalysts for catalytic incineration of toluene.lld:pubmed
pubmed-article:14720541pubmed:affiliationDepartment of Chemical Engineering, Kao Yuan Institute of Technology, Kaohsiung 821, Taiwan, ROC. huei@cc.kyit.edu.twlld:pubmed
pubmed-article:14720541pubmed:publicationTypeJournal Articlelld:pubmed