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pubmed-article:12967307pubmed:abstractText[reaction: see text] An approach to the highly functionalized tricyclic core of guanacastepene A has been developed using a rhodium(I)-catalyzed allenic Pauson-Khand reaction. This approach constitutes a conceptually novel strategy for the synthesis of this tricyclic framework, whereby the six-membered ring is formed intially followed by simultaneous formation of the five- and seven-membered rings.lld:pubmed
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pubmed-article:12967307pubmed:dateRevised2007-11-14lld:pubmed
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pubmed-article:12967307pubmed:articleTitleUnique strategy for the assembly of the carbon skeleton of guanacastepene A using an allenic Pauson-Khand-type reaction.lld:pubmed
pubmed-article:12967307pubmed:affiliationDepartment of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260, USA. kbrummon@pitt.edulld:pubmed
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