| pubmed-article:12783550 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0205103 | lld:lifeskim |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0012771 | lld:lifeskim |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0679622 | lld:lifeskim |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0205314 | lld:lifeskim |
| pubmed-article:12783550 | lifeskim:mentions | umls-concept:C0068882 | lld:lifeskim |
| pubmed-article:12783550 | pubmed:issue | 23 | lld:pubmed |
| pubmed-article:12783550 | pubmed:dateCreated | 2003-6-4 | lld:pubmed |
| pubmed-article:12783550 | pubmed:abstractText | A novel anionic RSN(O)SR species, the intermediate in transnitrosation reactions, was explored computationally with B3LYP and CBS-QB3 methods. The species resembles a nitroxyl coordinated to a highly distorted disulfide, and it differs significantly from intermediates in nucleophilic acyl substitution. Reactions of the following species were computed for comparison: MeS(-) + MeSNO; MeO(-) + MeONO; MeS(-) + MeSCHO; MeO(-) + MeOCHO. The last two have very different intermediates from the first two. Mass spectrometric experimental evidence is presented that is consistent with the formation of a nitroxyl disulfide in the gas phase. The calculated proton affinity and redox potentials of the intermediate are also reported. | lld:pubmed |
| pubmed-article:12783550 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:language | eng | lld:pubmed |
| pubmed-article:12783550 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:12783550 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12783550 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:12783550 | pubmed:month | Jun | lld:pubmed |
| pubmed-article:12783550 | pubmed:issn | 0002-7863 | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:HoukK NKN | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:StamlerJonath... | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:TooneEric JEJ | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:VoyksnerRober... | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:BartbergerMic... | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:ChoiBo YoonBY | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:McCarrenPatri... | lld:pubmed |
| pubmed-article:12783550 | pubmed:author | pubmed-author:HietbrinkBruc... | lld:pubmed |
| pubmed-article:12783550 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:12783550 | pubmed:day | 11 | lld:pubmed |
| pubmed-article:12783550 | pubmed:volume | 125 | lld:pubmed |
| pubmed-article:12783550 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:12783550 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:12783550 | pubmed:pagination | 6972-6 | lld:pubmed |
| pubmed-article:12783550 | pubmed:dateRevised | 2007-11-14 | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:meshHeading | pubmed-meshheading:12783550... | lld:pubmed |
| pubmed-article:12783550 | pubmed:year | 2003 | lld:pubmed |
| pubmed-article:12783550 | pubmed:articleTitle | Nitroxyl disulfides, novel intermediates in transnitrosation reactions. | lld:pubmed |
| pubmed-article:12783550 | pubmed:affiliation | Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, California 90095-1569, USA. houk@chem.ucla.edu | lld:pubmed |
| pubmed-article:12783550 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:12783550 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |
| pubmed-article:12783550 | pubmed:publicationType | Research Support, U.S. Gov't, Non-P.H.S. | lld:pubmed |
| pubmed-article:12783550 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:12783550 | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:12783550 | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:12783550 | lld:pubmed |
