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pubmed-article:12597631pubmed:abstractTextIn recent years capillary chromatography has gained popularity for trace analyses. Most often UV or electrochemical detection is employed because the small peak volumes make post-column derivatization challenging. We have developed a simple method based on flow injection for determining contributions to peak broadening from post-column reactors. The only requirement for application of our methodology is that diffusion be in the Taylor regime so that radial concentration gradients are relaxed enabling mixing purely by diffusion.lld:pubmed
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pubmed-article:12597631pubmed:dateRevised2009-1-15lld:pubmed
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pubmed-article:12597631pubmed:articleTitleSimple method for the quantitative examination of extra column band broadening in microchromatographic systems.lld:pubmed
pubmed-article:12597631pubmed:affiliationDepartment of Chemistry, University of Pittsburgh, 219 Parkman Avenue, Pittsburgh, PA 15260, USA.lld:pubmed
pubmed-article:12597631pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:12597631pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed
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