| pubmed-article:12467442 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0025664 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0184661 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C1521827 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0679622 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0205314 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0127400 | lld:lifeskim |
| pubmed-article:12467442 | lifeskim:mentions | umls-concept:C0072594 | lld:lifeskim |
| pubmed-article:12467442 | pubmed:issue | 25 | lld:pubmed |
| pubmed-article:12467442 | pubmed:dateCreated | 2002-12-6 | lld:pubmed |
| pubmed-article:12467442 | pubmed:abstractText | 2-Alkylidenecycloalkanones are powerful synthons used as the key intermediates in many important syntheses. Because of their potential, a general method of preparation from readily available starting materials, under very mild conditions, was considered to be worthwhile. Cerium(III) chloride heptahydrate in combination with sodium iodide in refluxing acetonitrile promotes a regio- and stereoselective beta-elimination reaction to (E)-2-alkylidenecycloalkanones in 2-(1-hydroxyalkyl)cycloalkanones. The synthetic value of the present procedure is demonstrated by the synthesis of monoterpene (S)-(-)-pulegone (8) in its optically active form. | lld:pubmed |
| pubmed-article:12467442 | pubmed:language | eng | lld:pubmed |
| pubmed-article:12467442 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12467442 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:12467442 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12467442 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12467442 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12467442 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:12467442 | pubmed:month | Dec | lld:pubmed |
| pubmed-article:12467442 | pubmed:issn | 0022-3263 | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:BartoliGiusep... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:MarcantoniEnr... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:MecozziTizian... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:TorregianiEli... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:DalpozzoRenat... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:BoscoMarcella... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:GiulianiArian... | lld:pubmed |
| pubmed-article:12467442 | pubmed:author | pubmed-author:SambriLetizia... | lld:pubmed |
| pubmed-article:12467442 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:12467442 | pubmed:day | 13 | lld:pubmed |
| pubmed-article:12467442 | pubmed:volume | 67 | lld:pubmed |
| pubmed-article:12467442 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:12467442 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:12467442 | pubmed:pagination | 9111-4 | lld:pubmed |
| pubmed-article:12467442 | pubmed:dateRevised | 2006-11-15 | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:meshHeading | pubmed-meshheading:12467442... | lld:pubmed |
| pubmed-article:12467442 | pubmed:year | 2002 | lld:pubmed |
| pubmed-article:12467442 | pubmed:articleTitle | An efficient procedure for the preparation of (E)-alpha-alkylidenecycloalkanones mediated by a CeCl(3) x 7H(2)O-NaI system. Novel methodology for the synthesis of (S)-(-)-pulegone. | lld:pubmed |
| pubmed-article:12467442 | pubmed:affiliation | Department of Chemical Sciences, University of Camerino, via S. Agostino 1, I-62032 Camerino (MC), Italy. | lld:pubmed |
| pubmed-article:12467442 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:12467442 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
