| pubmed-article:12137516 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C0443286 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C1705165 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C0598128 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C1527177 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C0441513 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C1260969 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C2700061 | lld:lifeskim |
| pubmed-article:12137516 | lifeskim:mentions | umls-concept:C0449445 | lld:lifeskim |
| pubmed-article:12137516 | pubmed:issue | 30 | lld:pubmed |
| pubmed-article:12137516 | pubmed:dateCreated | 2002-7-24 | lld:pubmed |
| pubmed-article:12137516 | pubmed:abstractText | Transition metal-catalyzed cycloaddition reactions represent powerful methods for the construction of complex polycyclic systems. We have developed a new intermolecular metal-catalyzed [4 + 2 + 2] cycloaddition of heteroatom-tethered enyne derivatives with 1,3-butadiene. This study demonstrates that excellent selectivity can be obtained for the heterocycloaddition adducts through the judicious choice of silver salt. The development of the tandem rhodium-catalyzed allylic substitution [4 + 2 + 2] cycloaddition provides a convenient three-component coupling that circumvents the prior formation of the enyne derivative. Finally, the introduction of a stereogenic center at C-2 leads to a diastereoselective cycloaddition, which provides a powerful new method for the construction of bicyclic octanoid ring systems applicable to target directed synthesis. | lld:pubmed |
| pubmed-article:12137516 | pubmed:grant | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:commentsCorrections | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:language | eng | lld:pubmed |
| pubmed-article:12137516 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:12137516 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:12137516 | pubmed:month | Jul | lld:pubmed |
| pubmed-article:12137516 | pubmed:issn | 0002-7863 | lld:pubmed |
| pubmed-article:12137516 | pubmed:author | pubmed-author:FazalAleem... | lld:pubmed |
| pubmed-article:12137516 | pubmed:author | pubmed-author:EvansP... | lld:pubmed |
| pubmed-article:12137516 | pubmed:author | pubmed-author:RobinsonJohn... | lld:pubmed |
| pubmed-article:12137516 | pubmed:author | pubmed-author:BaumErich WEW | lld:pubmed |
| pubmed-article:12137516 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:12137516 | pubmed:day | 31 | lld:pubmed |
| pubmed-article:12137516 | pubmed:volume | 124 | lld:pubmed |
| pubmed-article:12137516 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:12137516 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:12137516 | pubmed:pagination | 8782-3 | lld:pubmed |
| pubmed-article:12137516 | pubmed:dateRevised | 2008-1-17 | lld:pubmed |
| pubmed-article:12137516 | pubmed:meshHeading | pubmed-meshheading:12137516... | lld:pubmed |
| pubmed-article:12137516 | pubmed:meshHeading | pubmed-meshheading:12137516... | lld:pubmed |
| pubmed-article:12137516 | pubmed:meshHeading | pubmed-meshheading:12137516... | lld:pubmed |
| pubmed-article:12137516 | pubmed:meshHeading | pubmed-meshheading:12137516... | lld:pubmed |
| pubmed-article:12137516 | pubmed:meshHeading | pubmed-meshheading:12137516... | lld:pubmed |
| pubmed-article:12137516 | pubmed:year | 2002 | lld:pubmed |
| pubmed-article:12137516 | pubmed:articleTitle | Intermolecular transition metal-catalyzed [4 + 2 + 2] cycloaddition reactions: a new approach to the construction of eight-membered rings. | lld:pubmed |
| pubmed-article:12137516 | pubmed:affiliation | Department of Chemistry, Indiana University, Bloomington, Indiana 47405, USA. paevans@indiana.edu | lld:pubmed |
| pubmed-article:12137516 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:12137516 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |
| pubmed-article:12137516 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
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| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:12137516 | lld:pubmed |
