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pubmed-article:11684191pubmed:issue6lld:pubmed
pubmed-article:11684191pubmed:dateCreated2001-10-30lld:pubmed
pubmed-article:11684191pubmed:abstractTextChloroperoxidase from Caldariomyces fumago was able to chlorinate 17 of 20 aromatic hydrocarbons assayed in the presence of hydrogen peroxide and chloride ions. Reaction rates varied from 0.6 min(-1) for naphthalene to 758 min(-1) for 9-methylanthracene. Mono-, di- and tri-chlorinated compounds were obtained from the chloroperoxidase-mediated reaction on aromatic compounds. Dichloroacenaphthene, trichloroacenaphthene, 9,10-dichloroanthracene, chloropyrene, dichloropyrene, dichlorobiphenylene and trichlorobiphenylene were identified by mass spectral analyses as products from acenaphthene, anthracene, pyrene and biophenylene respectively. Polycyclic aromatic hydrocarbons with 5 and 6 aromatic rings were also substrates for the chloroperoxidase reaction. The importance of the microbial chlorination of aromatic pollutants and its potential environmental impact are discussed.lld:pubmed
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pubmed-article:11684191pubmed:issn0031-9422lld:pubmed
pubmed-article:11684191pubmed:authorpubmed-author:AyalaMMlld:pubmed
pubmed-article:11684191pubmed:authorpubmed-author:Vázquez-Duhal...lld:pubmed
pubmed-article:11684191pubmed:authorpubmed-author:Márquez-Rocha...lld:pubmed
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pubmed-article:11684191pubmed:volume58lld:pubmed
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pubmed-article:11684191pubmed:pagination929-33lld:pubmed
pubmed-article:11684191pubmed:dateRevised2006-11-15lld:pubmed
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pubmed-article:11684191pubmed:year2001lld:pubmed
pubmed-article:11684191pubmed:articleTitleBiocatalytic chlorination of aromatic hydrocarbons by chloroperoxidase of Caldariomyces fumago.lld:pubmed
pubmed-article:11684191pubmed:affiliationBiotechnology Institute UNAM, AP 510-3, Cuernavaca, 62271, Morelos, Mexico. vazqduh@ibt.unam.mxlld:pubmed
pubmed-article:11684191pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:11684191pubmed:publicationTypeResearch Support, Non-U.S. Gov'tlld:pubmed
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