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pubmed-article:11512788rdf:typepubmed:Citationlld:pubmed
pubmed-article:11512788lifeskim:mentionsumls-concept:C0242485lld:lifeskim
pubmed-article:11512788lifeskim:mentionsumls-concept:C0678553lld:lifeskim
pubmed-article:11512788pubmed:issuePt 2lld:pubmed
pubmed-article:11512788pubmed:dateCreated2001-8-21lld:pubmed
pubmed-article:11512788pubmed:abstractTextThe manganese perovskite system La(1-x)Ca(x)MnO3 displays a complex phase diagram of structural, magnetic, and transport properties with varying Ca concentration. At x = 2/3 and at low temperature, the system is antiferromagnetic with Mn4+ and Mn3+ ions occupying special positions in a charge-ordered supperlattice. The charge ordering transition at about 260 K is characterized by the appearance of satellite peaks around certain strong normal lattice reflections. The normal lattice reflections are due to scattering from planes containing Mn4+ and Mn3+ ions in nearly stoichiometric proportion, however the superlattice reflections are due to scattering from planes containing only Mn4+ ions. By measuring Diffraction Anomalous Fine-Structure spectral on a superlattice reflection and its associated normal lattice reflection, it is possible to isolate absorption-like spectra for the two Mn sites. Due to the weak intensity of these superlattice reflections, we were unable to obtain high quality near-edge spectra for the superlattice reflection measured. However, the data offer useful information about the local electronic structures of the two Mn ions.lld:pubmed
pubmed-article:11512788pubmed:languageenglld:pubmed
pubmed-article:11512788pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:11512788pubmed:statusPubMed-not-MEDLINElld:pubmed
pubmed-article:11512788pubmed:monthMarlld:pubmed
pubmed-article:11512788pubmed:issn0909-0495lld:pubmed
pubmed-article:11512788pubmed:authorpubmed-author:RavezPPlld:pubmed
pubmed-article:11512788pubmed:authorpubmed-author:FoxB GBGlld:pubmed
pubmed-article:11512788pubmed:authorpubmed-author:GrenierSSlld:pubmed
pubmed-article:11512788pubmed:authorpubmed-author:RenevierHHlld:pubmed
pubmed-article:11512788pubmed:issnTypePrintlld:pubmed
pubmed-article:11512788pubmed:day1lld:pubmed
pubmed-article:11512788pubmed:volume8lld:pubmed
pubmed-article:11512788pubmed:ownerNLMlld:pubmed
pubmed-article:11512788pubmed:authorsCompleteYlld:pubmed
pubmed-article:11512788pubmed:pagination384-6lld:pubmed
pubmed-article:11512788pubmed:dateRevised2003-10-31lld:pubmed
pubmed-article:11512788pubmed:year2001lld:pubmed
pubmed-article:11512788pubmed:articleTitleValence selective DAFS measurements of Mn in La1/3Ca2/3MnO3.lld:pubmed
pubmed-article:11512788pubmed:affiliationLaboratoire de Cristallographie, CNRS, Grenoble, France. ravel@phys.washington.edulld:pubmed
pubmed-article:11512788pubmed:publicationTypeJournal Articlelld:pubmed