Source:http://linkedlifedata.com/resource/pubmed/id/11196925
| Subject | Predicate | Object | Context |
|---|---|---|---|
| pubmed-article:11196925 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:11196925 | lifeskim:mentions | umls-concept:C1522492 | lld:lifeskim |
| pubmed-article:11196925 | lifeskim:mentions | umls-concept:C0150312 | lld:lifeskim |
| pubmed-article:11196925 | lifeskim:mentions | umls-concept:C0450363 | lld:lifeskim |
| pubmed-article:11196925 | lifeskim:mentions | umls-concept:C0078788 | lld:lifeskim |
| pubmed-article:11196925 | lifeskim:mentions | umls-concept:C0076299 | lld:lifeskim |
| pubmed-article:11196925 | pubmed:issue | 19 | lld:pubmed |
| pubmed-article:11196925 | pubmed:dateCreated | 2001-1-24 | lld:pubmed |
| pubmed-article:11196925 | pubmed:abstractText | Five new open-framework zinc phosphates, encompassing the entire hierarchy of open-framework structures, have been synthesized hydrothermally in the presence of triethylenetetramine. The structures include one-dimensional ladders, two-dimensional layers, and three-dimensional structures as well as a zinc phosphate where the amine acts as a ligand. [C6N4H22]0.5[Zn(HPO4)2] (I): monoclinic, space group P2(1)/c (no. 14), a = 5.2677(1) A, b = 13.3025(1) A, c = 14.7833(1) A, beta = 96.049 degrees, Z = 4. [C6N4H22]0.5[Zn2(HPO4)3] (II): triclinic, space group P1 (no. 2), a = 7.515(1) A, b = 8.2553(1) A, c = 12.911(1) A, alpha = 98.654(1) degrees, beta = 101.274(1) degrees, gamma = 115.791(1) degrees, Z = 2. [C6N4H22]0.5[Zn2P2O8] (III): triclinic, space group P1 (no. 2), a = 8.064(1) A, b = 8.457(1) A, c = 9.023(1) A, alpha = 111.9(1) degrees, beta = 108.0(1) degrees, gamma = 103.6(1) degrees, Z = 2. [C6N4H22]0.5[Zn3(PO4)2(HPO4)] (IV): triclinic, space group P1 (no. 2), a = 5.218(1) A, b = 8.780(1) A, c = 16.081(1) A, alpha = 89.3(1) degrees, beta = 83.5(1) degrees, gamma = 74.3(1) degrees, Z = 2. [C6N4H20]0.5[Zn4P4O16] (V): monoclinic, space group P2(1)/c (no. 14), a = 9.219(1) A, b = 15.239(1) A, c = 10.227(1) A, beta = 105.2(1), Z = 4. The structure of I is composed of ZnO4 and HPO4 tetrahedra, which are edge-shared to form four-membered rings, which, in turn, form a one-dimensional chain (ladder). In II, these ladders are fused into a layer. The structures of III and IV comprise networks of ZnO4 and PO4 tetrahedra forming three-dimensional architectures. In V, the amine molecule coordinates to the Zn and acts as a pillar supporting the zinc phosphate layers, which possess infinite Zn-O-Zn linkages. The 16-membered one-dimensional channel in IV and the ZnO3N pillar, along with infinite Zn-O-Zn linkages in V, are novel features. The structure of the open-framework zinc phosphates is found to depend sensitively on the relative concentrations of the amine and phosphoric acid, with high concentrations of the latter favoring structures with lower dimensions. | lld:pubmed |
| pubmed-article:11196925 | pubmed:language | eng | lld:pubmed |
| pubmed-article:11196925 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:11196925 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:11196925 | pubmed:month | Sep | lld:pubmed |
| pubmed-article:11196925 | pubmed:issn | 0020-1669 | lld:pubmed |
| pubmed-article:11196925 | pubmed:author | pubmed-author:NatarajanSS | lld:pubmed |
| pubmed-article:11196925 | pubmed:author | pubmed-author:RaoC NCN | lld:pubmed |
| pubmed-article:11196925 | pubmed:author | pubmed-author:ChoudhuryAA | lld:pubmed |
| pubmed-article:11196925 | pubmed:issnType | lld:pubmed | |
| pubmed-article:11196925 | pubmed:day | 18 | lld:pubmed |
| pubmed-article:11196925 | pubmed:volume | 39 | lld:pubmed |
| pubmed-article:11196925 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:11196925 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:11196925 | pubmed:pagination | 4295-304 | lld:pubmed |
| pubmed-article:11196925 | pubmed:dateRevised | 2003-10-31 | lld:pubmed |
| pubmed-article:11196925 | pubmed:year | 2000 | lld:pubmed |
| pubmed-article:11196925 | pubmed:articleTitle | Formation of one-, two-, and three-dimensional open-framework zinc phosphates in the presence of a tetramine. | lld:pubmed |
| pubmed-article:11196925 | pubmed:affiliation | Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur P.O., Bangalore 560 064, India. | lld:pubmed |
| pubmed-article:11196925 | pubmed:publicationType | Journal Article | lld:pubmed |
| http://linkedlifedata.com/r... | pubmed:referesTo | pubmed-article:11196925 | lld:pubmed |