pubmed-article:10575967 | rdf:type | pubmed:Citation | lld:pubmed |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C0220825 | lld:lifeskim |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C2717789 | lld:lifeskim |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C0772162 | lld:lifeskim |
pubmed-article:10575967 | lifeskim:mentions | umls-concept:C0078814 | lld:lifeskim |
pubmed-article:10575967 | pubmed:issue | 22 | lld:pubmed |
pubmed-article:10575967 | pubmed:dateCreated | 1999-12-9 | lld:pubmed |
pubmed-article:10575967 | pubmed:abstractText | We synthesized a novel aromatic polymer-coated zirconia-based RPLC stationary phase by chemical adsorption of a copolymer of chloromethylstyrene and diethoxymethylvinylsilane onto zirconia (CMS/VMS-ZrO2). Characterization of the pore structure of the support by nitrogen porosimetry and inverse size-exclusion chromatography indicates that CMS/VMS-ZrO2 maintains the well-defined pore structure of the base material. Flow studies show that CMS/VMS-ZrO2 has good mass transfer characteristics. The reversed-phase retention characteristics of the new support are comparable to those of conventional silica-bonded phases. We have also evaluated the mechanical, thermal, and pH stability of CMS/VMS-ZrO2. The results show that CMS/VMS-ZrO2 is stable over a very wide range of pH (pH = 1-13) and at temperatures as high as 160 degrees C. Chromatographic separations of some low molecular weight aromatic analytes on CMS/VMS-ZrO2 and octadecyl-bonded silica phases indicate that there are some subtle but significant differences in the chromatographic selectivity of these two types of phases. | lld:pubmed |
pubmed-article:10575967 | pubmed:language | eng | lld:pubmed |
pubmed-article:10575967 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:10575967 | pubmed:citationSubset | IM | lld:pubmed |
pubmed-article:10575967 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:10575967 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:10575967 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
pubmed-article:10575967 | pubmed:status | MEDLINE | lld:pubmed |
pubmed-article:10575967 | pubmed:month | Nov | lld:pubmed |
pubmed-article:10575967 | pubmed:issn | 0003-2700 | lld:pubmed |
pubmed-article:10575967 | pubmed:author | pubmed-author:CarrP WPW | lld:pubmed |
pubmed-article:10575967 | pubmed:author | pubmed-author:ZhaoJJ | lld:pubmed |
pubmed-article:10575967 | pubmed:issnType | Print | lld:pubmed |
pubmed-article:10575967 | pubmed:day | 15 | lld:pubmed |
pubmed-article:10575967 | pubmed:volume | 71 | lld:pubmed |
pubmed-article:10575967 | pubmed:owner | NLM | lld:pubmed |
pubmed-article:10575967 | pubmed:authorsComplete | Y | lld:pubmed |
pubmed-article:10575967 | pubmed:pagination | 5217-24 | lld:pubmed |
pubmed-article:10575967 | pubmed:dateRevised | 2006-11-15 | lld:pubmed |
pubmed-article:10575967 | pubmed:meshHeading | pubmed-meshheading:10575967... | lld:pubmed |
pubmed-article:10575967 | pubmed:meshHeading | pubmed-meshheading:10575967... | lld:pubmed |
pubmed-article:10575967 | pubmed:meshHeading | pubmed-meshheading:10575967... | lld:pubmed |
pubmed-article:10575967 | pubmed:year | 1999 | lld:pubmed |
pubmed-article:10575967 | pubmed:articleTitle | Synthesis and evaluation of an aromatic polymer-coated zirconia for reversed-phase liquid chromatography. | lld:pubmed |
pubmed-article:10575967 | pubmed:affiliation | Department of Chemistry, University of Minnesota, Minneapolis 55455, USA. | lld:pubmed |
pubmed-article:10575967 | pubmed:publicationType | Journal Article | lld:pubmed |
pubmed-article:10575967 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |