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pubmed-article:10574213pubmed:abstractTextNonaqueous capillary electrophoresis (NACE) is a relatively new area with several advantages that include enhanced efficiency and improved detection sensitivity. The goal of this study was to investigate the influence of NACE compared to aqueous CE on the separation efficiency of oligosaccharides. The applied voltage and buffer concentration were optimized for the aqueous and nonaqueous buffer media to minimize the band broadening effects of Joule heating and electrophoretic dispersion. At the optimized conditions a 1.5-fold enhancement in efficiency was obtained with the nonaqueous buffer medium.lld:pubmed
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pubmed-article:10574213pubmed:authorpubmed-author:WardV LVLlld:pubmed
pubmed-article:10574213pubmed:authorpubmed-author:KhalediM GMGlld:pubmed
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pubmed-article:10574213pubmed:dateRevised2009-1-15lld:pubmed
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pubmed-article:10574213pubmed:year1999lld:pubmed
pubmed-article:10574213pubmed:articleTitleEfficiency studies in nonaqueous capillary electrophoresis.lld:pubmed
pubmed-article:10574213pubmed:affiliationDepartment of Chemistry, North Carolina State University, Raleigh 27695-8204, USA.lld:pubmed
pubmed-article:10574213pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:10574213pubmed:publicationTypeResearch Support, U.S. Gov't, P.H.S.lld:pubmed