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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
18
pubmed:dateCreated
2009-9-8
pubmed:abstractText
Enhancing the optical emission of cerium oxide nanoparticles is essential for potential biomedical applications. In the present work, we report a simple chemical precipitation technique to synthesize europium-doped cerium oxide nanostructures to enhance the emission properties. Structural and optical properties showed an acute dependence on the concentration of oxygen ion vacancy and trivalent cerium, which, in turn, could be modified by dopant concentration and the annealing temperature. Results from X-ray photoelectron spectroscopy showed an increase in tetravalent cerium concentration to 85% on annealing at 900 degrees C. The concentration of oxygen ion vacancy increased from 1.7x10(20) cm(-3) to 4.1x10(20) cm(-3) with the increase in dopant concentration. Maximum emission at room temperature was obtained for 15 mol % Eu-doped ceria, which improved with annealing temperature. The role of oxygen ion vacancies and trivalent cerium in modifying the emission properties is discussed.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Sep
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
25
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
10998-1007
pubmed:year
2009
pubmed:articleTitle
Luminescence properties of europium-doped cerium oxide nanoparticles: role of vacancy and oxidation states.
pubmed:affiliation
Advanced Materials Processing and Analysis Center (AMPAC), Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL 32816, USA.
pubmed:publicationType
Journal Article