Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
11
pubmed:dateCreated
2009-3-18
pubmed:abstractText
Owing to wide-ranging industrial applications and fundamental importance, tailored synthesis of well-faceted single crystals of anatase TiO(2) with high percentage of reactive facets has attracted much research interest. In this work, high-quality anatase TiO(2) single-crystal nanosheets mainly dominated by {001} facets have been prepared by using a water-2-propanol solvothermal synthetic route. The synergistic functions of 2-propanol and HF on the growth of anatase TiO(2) single-crystal nanosheets were studied by first-principle theoretical calculations, revealing that the addition of 2-propanol can strengthen the stabilization effect associated with fluorine adsorption over (001) surface and thus stimulate its preferred growth. By measuring the (*)OH species with terephthalic acid scavenger, the as-prepared anatase TiO(2) single-crystal nanosheets having 64% {001} facets show superior photoreactivity (more than 5 times), compared to P25 as a benchmarking material.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
25
pubmed:volume
131
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4078-83
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Solvothermal synthesis and photoreactivity of anatase TiO(2) nanosheets with dominant {001} facets.
pubmed:affiliation
The University of Queensland, ARC Centre of Excellence for Functional Nanomaterials.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't