Linked Life Data

17877407

Source:http://linkedlifedata.com/resource/pubmed/id/17877407

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pubmed-article:17877407pubmed:dateCreated2007-10-5lld:pubmed
pubmed-article:17877407pubmed:abstractTextA novel fluorous-tagged ammonia surrogate has been synthesized and its application to the synthesis of anilines by Buchwald-Hartwig palladium-catalyzed amidation-hydrolysis protocol is described. Primary anilines were obtained in moderate to good yields after a sequence of two reaction steps involving fluorous separation techniques for their purification. Preliminary results indicate that N-substituted anilines can also be obtained using just N-substituted-FBoc carbamates as the nitrogen source.lld:pubmed
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pubmed-article:17877407pubmed:year2007lld:pubmed
pubmed-article:17877407pubmed:articleTitleFluorous-tagged carbamates for the pd-catalyzed amination of aryl halides.lld:pubmed
pubmed-article:17877407pubmed:affiliationJohnson and Johnson Pharmaceutical Research and Development, Research and Early Development Europe, CNS-Psychiatry, Division of Janssen-Cilag, Medicinal Chemistry Department, Jarama 75, 45007 Toledo, Spain. atrabanc@prdes.jnj.comlld:pubmed
pubmed-article:17877407pubmed:publicationTypeJournal Articlelld:pubmed
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