Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
16
pubmed:dateCreated
2007-9-18
pubmed:abstractText
A large (ca 0.7 L) wire-cylinder benchtop reactor was developed and tested for DC corona processing of VOC (volatile organic compound)-contaminated air at room temperature and pressure. The aim of our research is the identification and rationalization of the chemical reactions responsible for VOC removal. Model hydrocarbons, n-hexane and 2,2,4-trimethylpentane (i-octane), were used to characterize the process and compare the effects of DC corona polarity and of humidity on its energy efficiency and products. n-Hexane and i-octane behave very similarly. For both, the energy efficiency is significantly better with negative than with positive DC corona, especially in humid air. The effect of humidity is most interesting. Thus, while with -DC corona the process efficiency is significantly better in humid air, a slight inhibition is observed with +DC corona. Differences between +DC and -DC corona are also found in the amounts of volatile products formed, which include CO2, CO, and minor quantities of organic byproducts (aldehydes, ketones, alcohols, and lower hydrocarbons). A significant fraction of the carbon originally present as VOC is, however, unaccounted for by the analysis of gaseous and volatile organic products and must, therefore, end up as nonvolatile materials and aerosols.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
0013-936X
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
41
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5862-8
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
DC corona electric discharges for air pollution control. Part 1. Efficiency and products of hydrocarbon processing.
pubmed:affiliation
Department of Chemical Sciences, Università di Padova, 35131 Padova, Italy.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't