| pubmed-article:20449421 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0036311 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0682906 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0220781 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C1704332 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0023688 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C1883254 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0024488 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0563532 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0678594 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C2827424 | lld:lifeskim |
| pubmed-article:20449421 | lifeskim:mentions | umls-concept:C0871161 | lld:lifeskim |
| pubmed-article:20449421 | pubmed:issue | 7 | lld:pubmed |
| pubmed-article:20449421 | pubmed:dateCreated | 2010-5-7 | lld:pubmed |
| pubmed-article:20449421 | pubmed:abstractText | Two enantiomeric Schiff base ligands R-/S-H2L in situ generated from the condensation of o-vanillin with R- or S-2-phenylglycinol were applied to assemble chiral multinuclear transition metal magnetic clusters for the first time. Four new enantiomerically pure chiral clusters, [NaMn4(3-O)(N3)1.75Br0.25(R-L)3(MeOH)2(H2O)2][NaMn4(mu3-O)(N3)2(R-L)3(MeOH)2(H2O)2]Br4 (1R), [NaMn4(mu3-O)(N3)1.75Br0.25(S-L)3(MeOH)2(H2O)2][NaMn4(mu3-O)(N3)2(S-L)3(MeOH)2(H2O)2]Br4 (1S), [Cu6(R-L)2(R-HL)2(N3)5(MeOH)]NO3.2MeOH.H2O (2R) and [Cu6(S-L)2(S-HL)2(N3)5(MeOH)]NO3.2MeOH.H2O (2S), have been synthesized and characterized by single crystal X-ray crystallography and CD spectroscopy. Three Mn(III) in the MnIIMnIII3 clusters of 1R and 1S are joined together through the 3-O bridge to form an oxo-centered Mn3O unit. Three L2- link four manganese atoms via the mu2-O,N,O-bridging manner into a MnIIMnIII3 cluster in a distorted tetrahedral geometry. Enantiomeric 2S and 2R are hexanuclear copper(II) clusters composed of a cubane-like Cu4L4 part with a dinuclear Cu2(N3)2 unit capped on one of the faces of the Cu4L4 cubane via the mu1,1-azide and phenolate bridges from the chiral ligands. Magnetic analysis reveals intracluster antiferromagnetic interaction between adjacent manganese ions in chiral oxo-centered MnIIMnIII3 magnetic clusters for 1R and 1S, and dominating antiferromagnetic over weak ferromagnetic interactions in Cu6 clusters in 2R and 2S. | lld:pubmed |
| pubmed-article:20449421 | pubmed:language | eng | lld:pubmed |
| pubmed-article:20449421 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20449421 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:20449421 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20449421 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20449421 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:20449421 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:20449421 | pubmed:month | Feb | lld:pubmed |
| pubmed-article:20449421 | pubmed:issn | 1477-9234 | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:TongMing-Lian... | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:LeiYunY | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:HerchelRadova... | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:FanLin-LinLL | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:LengJi-DongJD | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:OuYong-CongYC | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:LinZhuo-JiaZJ | lld:pubmed |
| pubmed-article:20449421 | pubmed:author | pubmed-author:GuoFu-ShengFS | lld:pubmed |
| pubmed-article:20449421 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:20449421 | pubmed:day | 21 | lld:pubmed |
| pubmed-article:20449421 | pubmed:volume | 39 | lld:pubmed |
| pubmed-article:20449421 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:20449421 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:20449421 | pubmed:pagination | 1771-80 | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:meshHeading | pubmed-meshheading:20449421... | lld:pubmed |
| pubmed-article:20449421 | pubmed:year | 2010 | lld:pubmed |
| pubmed-article:20449421 | pubmed:articleTitle | Chiral transition metal clusters from two enantiomeric schiff base ligands. Synthesis, structures, CD spectra and magnetic properties. | lld:pubmed |
| pubmed-article:20449421 | pubmed:affiliation | Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China. | lld:pubmed |
| pubmed-article:20449421 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:20449421 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
