Source:http://linkedlifedata.com/resource/pubmed/id/19885484
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
44
|
| pubmed:dateCreated |
2009-11-3
|
| pubmed:abstractText |
Significant Rh-NH p-bonding in formally 16-electron(eta5-C5Me5)Rh(XNC6H4NX') (X, X' = H or Ts) is shownby structural features and by DFT calculations;(eta5-C5Me5)Rh(TsNC6H4NH) is the fastest transfer hydrogenationcatalyst of the three complexes and generates a formate complexunder catalytic conditions.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
|
| pubmed:chemical | |
| pubmed:status |
MEDLINE
|
| pubmed:month |
Nov
|
| pubmed:issn |
1364-548X
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
28
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
6801-3
|
| pubmed:meshHeading | |
| pubmed:year |
2009
|
| pubmed:articleTitle |
Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.
|
| pubmed:affiliation |
Piramal Healthcare, Leeds Road, Huddersfield, UKHD1 9GA.
|
| pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|