| pubmed-article:19366204 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0014996 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0022634 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0185125 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C2603343 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0598002 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0596258 | lld:lifeskim |
| pubmed-article:19366204 | lifeskim:mentions | umls-concept:C0596513 | lld:lifeskim |
| pubmed-article:19366204 | pubmed:issue | 10 | lld:pubmed |
| pubmed-article:19366204 | pubmed:dateCreated | 2009-5-8 | lld:pubmed |
| pubmed-article:19366204 | pubmed:abstractText | Synthesis of alpha-CF(3) carbonyl compounds has been recognized to be difficult up to now because the polarization of CF(3)(delta-)-I(delta+) is opposite to that of CH(3)(delta+)-I(delta-), and this makes it difficult to introduce CF(3)(+) unit to enolates. We recently reported an effective alpha-trifluoromethylation of ketones by using Et(2)Zn with Rh catalyst, but the mechanism has not fully been cleared. Now, we carried out the detailed mechanistic studies and found the involvement of a highly reactive alkylrhodium complex which derived from Et(2)Zn and RhCl(PPh(3))(3) in this alpha-trifluoromethylation. Furthermore, this alpha-trifluoromethylation was applied to other types of carbonyl compounds in good yields. | lld:pubmed |
| pubmed-article:19366204 | pubmed:language | eng | lld:pubmed |
| pubmed-article:19366204 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:19366204 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:19366204 | pubmed:month | May | lld:pubmed |
| pubmed-article:19366204 | pubmed:issn | 1520-6904 | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:AndoAkiraA | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:SatoKazuyukiK | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:YamaguchiRyoj... | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:OmoteMasaakiM | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:KumadakiItsum... | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:TaruiAtsushiA | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:YukiTakashiT | lld:pubmed |
| pubmed-article:19366204 | pubmed:author | pubmed-author:HamanoTetsuya... | lld:pubmed |
| pubmed-article:19366204 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:19366204 | pubmed:day | 15 | lld:pubmed |
| pubmed-article:19366204 | pubmed:volume | 74 | lld:pubmed |
| pubmed-article:19366204 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:19366204 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:19366204 | pubmed:pagination | 3815-9 | lld:pubmed |
| pubmed-article:19366204 | pubmed:meshHeading | pubmed-meshheading:19366204... | lld:pubmed |
| pubmed-article:19366204 | pubmed:meshHeading | pubmed-meshheading:19366204... | lld:pubmed |
| pubmed-article:19366204 | pubmed:meshHeading | pubmed-meshheading:19366204... | lld:pubmed |
| pubmed-article:19366204 | pubmed:meshHeading | pubmed-meshheading:19366204... | lld:pubmed |
| pubmed-article:19366204 | pubmed:meshHeading | pubmed-meshheading:19366204... | lld:pubmed |
| pubmed-article:19366204 | pubmed:year | 2009 | lld:pubmed |
| pubmed-article:19366204 | pubmed:articleTitle | Mechanistic studies on alpha-trifluoromethylation of ketones via silyl enol ethers and its application to other carbonyl compounds. | lld:pubmed |
| pubmed-article:19366204 | pubmed:affiliation | Faculty of Pharmaceutical Sciences, Setsunan University, 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, Japan. | lld:pubmed |
| pubmed-article:19366204 | pubmed:publicationType | Journal Article | lld:pubmed |
