Linked Life Data

19027229

Source:http://linkedlifedata.com/resource/pubmed/id/19027229

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-3
pubmed:dateCreated
2009-4-20
pubmed:abstractText
Hydroxylamine (HA) and hydroxylamine nitrate (HAN) have been involved independently in several tragic accidents, which incurred numerous fatalities and injuries. Following these incidents, adiabatic calorimetry and computational chemistry research was conducted on those compounds, suggesting potential reaction pathways of their decomposition, but the mechanism of their unstable behavior, still have not been completely understood. In the present work, isothermal decomposition tests were performed accompanied with HPLC, ion chromatography and UV analyses in the temperature range 80-160 degrees C. Condition-dependent autocatalytic decompositions were demonstrated for HA and HAN, and an intermediate formation has been observed that is most likely responsible for their autocatalytic behavior. These findings corroborate previously reported computational chemistry results.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1873-3336
pubmed:author
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
165
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
573-8
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Isothermal decomposition of hydroxylamine and hydroxylamine nitrate in aqueous solutions in the temperature range 80-160 degrees C.
pubmed:affiliation
Chemical Engineering Department, Mary Kay O'Connor Process Safety Center, Texas A&M University, College Station, TX 77843-3122, United States.
pubmed:publicationType
Journal Article