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rdf:type
lifeskim:mentions
pubmed:issue
25
pubmed:dateCreated
2008-7-22
pubmed:abstractText
Most statistical theories of anomalous diffusion rely on ensemble-averaged quantities such as the mean squared displacement. Single molecule tracking measurements require, however, temporal averaging. We contrast the two approaches in the case of continuous-time random walks with a power-law distribution of waiting times psi(t) proportional to t{-1-alpha}, with 0<alpha<1, lacking the mean. We show that, contrary to what is expected, the temporal averaged mean squared displacement leads to a simple diffusive behavior with diffusion coefficients that strongly differ from one trajectory to another. This distribution of diffusion coefficients renders a system inhomogeneous: an ensemble of simple diffusers with different diffusion coefficients. Taking an ensemble average over these diffusion coefficients results in an effective diffusion coefficient K{eff} approximately T{alpha-1} which depends on the length of the trajectory T.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
0031-9007
pubmed:author
pubmed:issnType
Print
pubmed:day
27
pubmed:volume
100
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
250602
pubmed:year
2008
pubmed:articleTitle
Nonergodicity mimics inhomogeneity in single particle tracking.
pubmed:affiliation
School of Chemistry, Raymond & Beverly Sackler Faculty of Exact Sciences, Tel-Aviv University, Tel Aviv 69978, Israel.
pubmed:publicationType
Journal Article