Linked Life Data

18278864

Source:http://linkedlifedata.com/resource/pubmed/id/18278864

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2008-3-11
pubmed:abstractText
2,4-N,N'-Disubstituted 1,3,5-triazapentadienyl ligands as their lithium salts [Li{(N(R)C(R'))2N}]2 [where R = SiMe3 here and hereafter and R' = dimethylamino (1) or 1-piperidino (2)] were synthesized via the reactions of LiN(SiMe3)2 with 2 equiv of the alpha-hydrogen-free carbonitrile dimethylcyanamide or 1-piperdinecarbonitrile and used in the isolation of the two-coordinate copper(I) complexes [Cu{(N(R)C(R'))2N}]2 [R' = dimethylamino (3) and 1-piperidino (4)]. Complex 2 features a twisted W-shaped ligand backbone in the solid state. Complexes 3 and 4 show an unusual 12-membered ring dinuclear copper( I) triazapentadienyl and a less expressed ability to form a stable delocalized triazapentadienyl system.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Mar
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
47
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1886-8
pubmed:year
2008
pubmed:articleTitle
Syntheses of 2,4-disubstituted 1,3,5-triazapentadienyl ligands having two guanidinato moieties and their use in the isolation of copper(I) complexes.
pubmed:affiliation
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People's Republic of China. mszhou@sxu.edu.cn
pubmed:publicationType
Journal Article