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rdf:type
lifeskim:mentions
pubmed:issue
25
pubmed:dateCreated
2006-7-20
pubmed:abstractText
This paper describes a new single molecule spectroscopy approach for the investigation of triplet-triplet and singlet-triplet interactions in conjugated polymers. The technique involves the irradiation of isolated single, mulitchromophoric, conjugated polymer molecules by a repetitive sequence of variable-intensity microsecond time scale excitation pulses. The fluorescence intensity is synchronously time-averaged for thousands of cycles of the pulse sequence to yield a high signal-to-noise fluorescence transient on the microsecond time scale. The transient can be analyzed with kinetic models to obtain quantitative information about the kinetics of triplet-triplet exciton annihilation and the quenching of singlet excitons by triplet excitons in conjugated polymers.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1520-6106
pubmed:author
pubmed:issnType
Print
pubmed:day
30
pubmed:volume
109
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
12366-71
pubmed:year
2005
pubmed:articleTitle
Single molecule modulation spectroscopy of conjugated polymers.
pubmed:affiliation
Center for Nano- and Molecular Science and Technology and Department of Chemistry and Biochemistry, University of Texas, Austin, Texas 78712, USA.
pubmed:publicationType
Journal Article