15524483

Source:http://linkedlifedata.com/resource/pubmed/id/15524483

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0022634, umls-concept:C0205314, umls-concept:C0679622, umls-concept:C2003941
pubmed:issue	23
pubmed:dateCreated	2004-11-4
pubmed:abstractText	Treatment of alpha,beta-unsaturated ketones with CF(3)I in the presence of Et(2)Zn and RhCl(PPh(3))(3) gave novel alpha-trifluoromethylation products in good yields. Hydrogen transfer from the ethyl group on the rhodium complex to the beta-position of the enone seems to play an important role in this reaction.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Nov
pubmed:issn	1523-7060
pubmed:author	pubmed-author:AndoAkiraA, pubmed-author:KumadakiItsumaroI, pubmed-author:OmoteMasaakiM, pubmed-author:SatoKazuyukiK
pubmed:issnType	Print
pubmed:day	11
pubmed:volume	6
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4359-61
pubmed:year	2004
pubmed:articleTitle	Rhodium-catalyzed novel trifluoromethylation at the alpha-position of alpha,beta-unsaturated ketones.
pubmed:affiliation	Faculty of Pharmaceutical Sciences, Setsunan University, Hirakata, Osaka 573-0101, Japan.
pubmed:publicationType	Journal Article