15524473

Source:http://linkedlifedata.com/resource/pubmed/id/15524473

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0039778, umls-concept:C0205131, umls-concept:C0302912, umls-concept:C1517004
pubmed:issue	23
pubmed:dateCreated	2004-11-4
pubmed:abstractText	Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals gave distinct EPR spectra thanks to surprisingly large beta-hydrogen atom hyperfine splittings that enabled them to be characterized and monitored. DFT computations indicated that the axial species (X = CH(2)) had a higher barrier to rotation about the (O)C(alpha)-C(beta) bond. The computed difference Delta H degrees for the axial and equatorial radicals (R = H, X = CH(2)) was 0.8 kcal mol(-)(1).
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Nov
pubmed:issn	1523-7060
pubmed:author	pubmed-author:DiLabioGino AGA, pubmed-author:IngoldKeith UKU, pubmed-author:RoydhouseMark DMD, pubmed-author:WaltonJohn CJC
pubmed:issnType	Print
pubmed:day	11
pubmed:volume	6
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4319-22
pubmed:year	2004
pubmed:articleTitle	Axial and equatorial cyclohexylacyl and tetrahydropyranyl-2-acyl radicals. An experimental and theoretical study.
pubmed:affiliation	National Institute for Nanotechnology, National Research Council of Canada, W6-010 ECERF, 9107 116th Street, Edmonton, AB, Canada T6G 2V4.
pubmed:publicationType	Journal Article