Linked Life Data

15147702

Source:http://linkedlifedata.com/resource/pubmed/id/15147702

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2004-5-18
pubmed:abstractText
The maximum absorption wavelengths (lambda(a-max)), absorption coefficient (epsilon), maximum emission wavelengths (lambda(e-max)) of 4-benzo[1,3]dioxol-5-ylmethylene-2-phenyl-4H-oxazol-5-one (1), 4-(3,4-dimethoxybenzylidene)-2-phenyl-4H-oxazol-5-one (2) and 4-(3,4,5-trimethoxy-benzylidene)-2-phenyl-4H-oxazol-5-one (3) were measured, their second-order nonlinear polarization values (beta(xxx)) were determined by solvatochromic method. Although the spectral nature (lambda(a-max), epsilon, lambda(e-max)) and beta(xxx) values of 1, 2 and 3 were close to each other in the same solvent, the second-order harmonic generation (SHG) value of sample 1 is higher obviously than that of sample 2 or 3 in solid state. The crystal structures of 1 and 2 characterized by single crystal X-ray diffraction technique indicated the reason why the SHG value of 1 is higher.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1386-1425
pubmed:author
pubmed:issnType
Print
pubmed:volume
60
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1587-91
pubmed:dateRevised
2008-11-21
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Study on the second-order optical behavior of 4-(substituted-benzylidene)-2-phenyl-4H-oxazol-5-one.
pubmed:affiliation
Department of Chemistry, Zhongshan University, Guangzhou 510275, China. songhuacan@hotmail.com
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't