Linked Life Data

12691897

Source:http://linkedlifedata.com/resource/pubmed/id/12691897

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
9
pubmed:dateCreated
2003-4-14
pubmed:abstractText
Electron beam irradiation of aqueous solutions containing different lead compounds (Pb(2+), (CH(3))(3)Pb(+), (C(2)H(5))(3)Pb(+)) was carried out. Formate and hydrogen peroxide were used as radical scavengers to elucidate the influence of the different species generated by water radiolysis. The precipitation of Pb(2+), only observed in the presence of formate, was attributed to COO(*-) but the nature of the precipitate is still unclear. Organolead compounds were shown to be efficiently degraded, probably converted into Pb(2+), using doses around 4 kGy. In the absence of scavengers, the degradation occurred according to the alkyl group stability. Both trialkyllead compounds were shown to be degraded by HO(*). On the contrary, the contribution of hydrogen atoms (H(*)) was shown to be highly dependent on the nature of the alkyl group, i.e. negligible for (C(2)H(5))(3)Pb(+) and more important for (CH(3))(3)Pb(+).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
0043-1354
pubmed:author
pubmed:issnType
Print
pubmed:volume
37
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2113-7
pubmed:dateRevised
2009-11-19
pubmed:meshHeading
pubmed:year
2003
pubmed:articleTitle
Degradation of organolead species in aqueous solutions by electron beam irradiation.
pubmed:affiliation
Laboratoire de Chimie Analytique et Minérale, UMR 7512 CNRS/ULP, Ecole Européenne de Chimie, Polymères & Matériaux, 25 rue Becquerel, Strasbourg Cedex 67087, France.
pubmed:publicationType
Journal Article