Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
30
pubmed:dateCreated
2002-7-24
pubmed:abstractText
In this communication, the presence of a persistent intramolecular C-H....O bond in solution, has been evidenced by NMR spectroscopy and theoretical calculations. The molecules under study were o-carboranyl beta-glycoside derivatives, in which, the donor group was the activated CH of the carboranyl residue and the acceptor atom was the glycosidic oxygen. The strength of the interaction and the geometry of the atoms involved were determined by ab initio calculations.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
31
pubmed:volume
124
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
8778-9
pubmed:dateRevised
2008-1-17
pubmed:meshHeading
pubmed:year
2002
pubmed:articleTitle
Evidences of strong C-H...O bond in an o-carboranyl beta-lactoside in solution.
pubmed:affiliation
Dipartimento di Scienze Chimiche e dei Biosistemi, Università di Siena, Via A. Moro, 2 - 53100 Siena, Italy. donatia@unisi.it
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't