12109085

Source:http://linkedlifedata.com/resource/pubmed/id/12109085

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0024467, umls-concept:C0066409, umls-concept:C0205250, umls-concept:C0314672, umls-concept:C0442825, umls-concept:C0596514, umls-concept:C1444748
pubmed:issue	11
pubmed:dateCreated	2002-7-11
pubmed:abstractText	The reaction of (BDI)MgiPr [BDI = HC(C(Me)=N-2,6-iPr2C6H3)2] with 2',4',6'-trimethylacetophenone in toluene affords the enolate complex [(BDI)Mg(mu-OC(=CH2)-2,4,6-Me3C6H2)]2 which is found to be an excellent initiator for the living, syndioselective (sigma r > 0.95) polymerisation of methyl methacrylate.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9610838
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jun
pubmed:issn	1359-7345
pubmed:author	pubmed-author:DoveAndrew PAP, pubmed-author:GibsonVernon CVC, pubmed-author:MarshallEdward LEL, pubmed-author:WhiteAndrew J PAJ, pubmed-author:WilliamsDavid JDJ
pubmed:issnType	Print
pubmed:day	7
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1208-9
pubmed:dateRevised	2003-11-3
pubmed:year	2002
pubmed:articleTitle	A well-defined magnesium enolate initiator for the living and highly syndioselective polymerisation of methylmethacrylate.
pubmed:affiliation	Department of Chemistry, Imperial College, South Kensington, London, UK SW7 2AY.
pubmed:publicationType	Journal Article