Source:http://linkedlifedata.com/resource/pubmed/id/11077281
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:dateCreated |
2000-12-13
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| pubmed:abstractText |
The crystal structure of the title complex, [Ni(C(6)H(14)N(2))(2)]Br(2), consists of discrete [Ni(C(6)H(14)N(2))(2)](2+) cations and bromide counter-anions. The Ni(II) ion is at the center of symmetry and is four-coordinated by four nitrogen donors of the mesocyclic ligand 1,5-diazacyclooctane (DACO) [Ni-N 1.935 (2)-1.937 (2) A]. The coordination geometry of Ni(II) can be considered as square planar and both DACO ligands take the boat-chair conformation. The bromide anions are hydrogen bonded with the nitrogen donors of the ligands to form a macrocycle-like ring system.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Nov
|
| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
56 Pt 11
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
1314-5
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| pubmed:dateRevised |
2003-10-31
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| pubmed:year |
2000
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| pubmed:articleTitle |
Bis(1,5-diazacyclooctane-N,N')nickel(II) dibromide.
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| pubmed:affiliation |
Department of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
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| pubmed:publicationType |
Journal Article
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