rdf:type |
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lifeskim:mentions |
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pubmed:issue |
5480
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pubmed:dateCreated |
2000-8-16
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pubmed:abstractText |
Crystals are generally considered to grow by attachment of ions to inorganic surfaces or organic templates. High-resolution transmission electron microscopy of biomineralization products of iron-oxidizing bacteria revealed an alternative coarsening mechanism in which adjacent 2- to 3-nanometer particles aggregate and rotate so their structures adopt parallel orientations in three dimensions. Crystal growth is accomplished by eliminating water molecules at interfaces and forming iron-oxygen bonds. Self-assembly occurs at multiple sites, leading to a coarser, polycrystalline material. Point defects (from surface-adsorbed impurities), dislocations, and slabs of structurally distinct material are created as a consequence of this growth mechanism and can dramatically impact subsequent reactivity.
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pubmed:commentsCorrections |
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
0036-8075
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pubmed:author |
|
pubmed:issnType |
Print
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pubmed:day |
4
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pubmed:volume |
289
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
751-4
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pubmed:dateRevised |
2008-11-21
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pubmed:meshHeading |
pubmed-meshheading:10926531-Betaproteobacteria,
pubmed-meshheading:10926531-Chemistry, Physical,
pubmed-meshheading:10926531-Colloids,
pubmed-meshheading:10926531-Crystallization,
pubmed-meshheading:10926531-Ferric Compounds,
pubmed-meshheading:10926531-Ferritins,
pubmed-meshheading:10926531-Hydrogen-Ion Concentration,
pubmed-meshheading:10926531-Hydroxides,
pubmed-meshheading:10926531-Iron Compounds,
pubmed-meshheading:10926531-Microscopy, Electron,
pubmed-meshheading:10926531-Minerals,
pubmed-meshheading:10926531-Oxidation-Reduction,
pubmed-meshheading:10926531-Physicochemical Phenomena
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pubmed:year |
2000
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pubmed:articleTitle |
Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products.
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pubmed:affiliation |
Department of Geology and Geophysics, University of Wisconsin-Madison, Madison, WI 53706, USA. jill@geology.wisc.edu
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.
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